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A systematic X-ray absorption spectroscopy investigation of the local coordination in gallium nanostructures has been performed as a function of temperature and particle size. It is shown that the nanostructure strongly affects the polymorphism of solid gallium and the (meta)stability range of the liquid phase (in agreement with previous works) and that the surface tension acts in the same direction as hydrostatic pressure in stabilizing the Ga solid phases. The effect of surface free energy is first to favor the metallic arrangement of the δ phase and then to stabilize a liquid-like phase based on dimeric molecules even at 90 K. The Ga−Ga distance in the dimers is lower in the liquid phase than in the α solid. The experimental results are discussed in comparison with molecular dynamic calculations to assess the presence of covalent character of the dimeric Ga2 units in liquid nanostructured gallium.
American Chemical Society
Publication date: 
27 Jun 2007

Paolo Ghigna, Giorgio Spinolo, Giovanni Battista Parravicini, Angiolino Stella, Andrea Migliori, Richard Kofman

Biblio References: 
Volume: 129 Issue: 25 Pages: 8026-8033
Journal of the American Chemical Society