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The piezoelectric potential screening by large excess electrons in nominally undoped ZnO has limited the energy conversion efficiency of the ZnO nanogenerators (NGs). In this study, we report a simple and effective approach to enhance the piezoelectric output performance of the ZnO NGs by forming a CuO–ZnO heterostructure. By depositing a ZnO thin film on the pre-deposited CuO thin film, which forms a p–n junction, excess electrons in ZnO can be effectively reduced. Thus, the piezoelectric potential generated in ZnO by an applied force can be less affected. Using this approach, we obtained an output voltage up to ∼7.5 V and a maximum current of 4.5 μA cm−2 measured under the forward connection, which is a 7-fold higher output voltage and an approximately one order of magnitude higher current density by comparison to the ZnO NGs without a CuO layer. Our results clearly demonstrate the effectiveness …
Royal Society of Chemistry
Publication date: 
1 Jan 2013

Sung-Ho Shin, Min Hyung Lee, Joo-Yun Jung, Jae Hun Seol, Junghyo Nah

Biblio References: 
Volume: 1 Issue: 48 Pages: 8103-8107
Journal of Materials Chemistry C