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‘All three-in-one’: ferromagnetic interactions, single-molecule magnetism and magnetocaloric properties in a new family of [Cu 4 Ln](Ln III= Gd, Tb, Dy) clusters

Type: 
Journal
Description: 
A new family of isomorphous [Cu4Ln] clusters (LnIII = Gd, Tb, Dy) with a ‘propeller’-like topology was obtained from the use of naphthalene-2,3-diol in CuII/LnIII chemistry; all complexes are ferromagnetically-coupled and display either magnetocaloric properties or SMM behavior depending on the central Ln ion.
Publisher: 
Royal Society of Chemistry
Publication date: 
1 Jan 2015
Authors: 

Paul Richardson, Dimitris I Alexandropoulos, Luís Cunha-Silva, Giulia Lorusso, Marco Evangelisti, Jinkui Tang, Theocharis C Stamatatos

Biblio References: 
Volume: 2 Issue: 10 Pages: 945-948
Origin: 
Inorganic Chemistry Frontiers
Link: 
https://pubs.rsc.org/--/content/articlehtml/2015/qi/c5qi00146c

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