Type:
Journal
Description:
The family of compounds of general formula [LnIII4TMII8(OH)8(L)8(O2CR)8(MeOH)y](ClO4)4 {[Gd4Zn8(OH)8(hmp)8(O2CiPr)8](ClO4)4 (1a); [Y4Zn8(OH)8(hmp)8(O2CiPr)8](ClO4)4 (1b); [Gd4Cu8(OH)8(hmp)8(O2CiPr)8](ClO4)4 (2a); [Y4Cu8(OH)8(hmp)8(O2CiPr)8](ClO4)4 (2b); [Gd4Cu8(OH)8(hep)8(O2CiPr)8](ClO4)4 (3a); [Gd4Cu8(OH)8(Hpdm)8(O2CtBu)8](ClO4)4 (4a); [Gd4Cu8(OH)8(ea)8(O2CMe)8](ClO4)4 (5a); [Gd4Ni8(OH)8(hmp)8(O2CEt)8(MeOH)6](ClO4)4 (6a); [Y4Ni8(OH)8(hmp)8(O2CEt)8(MeOH)6](ClO4)4 (6b); [Gd4Co8(OH)8(hmp)8(O2CEt)8(MeOH)6](ClO4)4 (7a); [Y4Co8(OH)8(hmp)8(O2CEt)8(MeOH)6](ClO4)4 (7b)} can be formed very simply and in high yields from the reaction of Ln(NO3)3·6H2O and TM(ClO4)2·6H2O and the appropriate ligand blend in a mixture of CH2Cl2 and MeOH in the presence of a suitable base. Remarkably, almost all the constituent parts, namely the lanthanide (or rare …
Publisher:
American Chemical Society
Publication date:
29 Sep 2016
Biblio References:
Volume: 55 Issue: 20 Pages: 10535-10546
Origin:
Inorganic chemistry