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The chalcogenide material Ge2Sb2Te5 is the prototype phase-change material, with widespread applications for optical media and random access memory. However, the full set of its independent elastic properties has not yet been published. In this study, we determine the elastic constants of the rocksalt Ge2Sb2Te5, experimentally by X-ray diffraction (XRD) and residual stress and computationally by density functional theory (DFT). The stiffnesses (XRD-stress/DFT) in GPa are C11 = 41/58, C12 = 7/8, and C44 = 8/12, and the Zener ratio is 0.46/0.48. These values are important to understand the effect of elastic distortions and nonmelting processes on the performances of increasingly small phase change data bits.
American Chemical Society
Publication date: 
17 Mar 2016

Raimondo Cecchini, Krisztian Kohary, Asunción Fernández, Marcello Cabibbo, Arnaud Marmier

Biblio References: 
Volume: 120 Issue: 10 Pages: 5624-5629
The Journal of Physical Chemistry C